Synthesis and Characterization of Novel Biological Mixed Organometallic Chromium (III) Complex of Potential Allyl-Sulfur Compounds of Garlic, Allicin

Volume 5 , Issue 1 , May 2002 , Pages 11-26

Authors

M. A. Andullah 1 ; D. I. Tofiq 1

1 College of Science, University of Sulaimani

DOI logo 10.17656/jzs.10085

Keywords

Abstract

From the readily acid and base hydrolysis (pH - dependence) of loosely Cr - S bond of bis (L- cysteinato)chromium (III) complexes, a biological mixed organometallic

- werner chromium complex, of trans - bis [(n3) s - allyl mercapto cysteinato ] chromium (III) hydroxide, has been synthesized via intermolecular insertion reaction of allyl sulfenic acid, which was extracted and isolated from natural garlic. This complex was characterized using IR, NMR, UV -Visible spectroscopic techniques and elemental analysis. Also biological activity of the prepared cormplex was tested in vitro.

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